keto-ABNO
| Grade : | for Organic Synthesis |
| Specification Assay : | 95.0+% (Capillary GC) |
| Storage Condition : | Keep at 2-10 degrees C. |
| Molecular Formula : | C8H12NO2 |
| Molecular Weight : | 154.19 |
Manufacturer : FUJIFILM Wako Pure Chemical Corporation
CAS RN® :
7123-92-4
| Catalogue/Product Number | Package Size | COA Download |
|---|---|---|
|
012-25003
|
1G | |
|
016-25001
|
100mg |
×
Document
Overview
Reaction
Oxidative Friedel-Crafts (CDC) Reaction
Oxidative Strecker Reaction
Oxidative aza-Diels-Alder Reaction
Keto-ABNO is a nitroxy radical type oxidation catalyst. Amines are oxidized to their corresponding imines efficiently with copper/keto-ABNO. By reacting of generated imine with a nucleophilic agent, α-amino acid derivative can be obtained. Also, the treatment of imine with a nucleophile gives stereoselective product when chiral ligand is used as asymmetric reaction.
Applications
| Precautions for Use | Packed on argon gas |
|---|
Property
| Appearance | Pale reddish yellow - yellow, crystals - powder |
|---|
Alias
- 9-Azabicyclo[3,3,1]nonan-3-one-N-oxyl